I have now published my theory of the atmosphere. Augmenting 19th Century Thermoelectric Greenhouse Theory with 20th Century Quantum Mechanics Raman Spectroscopy: Towards a Coherent Radiation Theory of the Atmosphere THE FULL COMPLEMENT OF GREENHOUSE GASES This is a diagram of all the vibrational modes ('absorption bands') of the Earth's atmospheric gases; in the near infrared range of the electromagnetic spectrum. Gases are detected by thermoelectric thermopile or bolometer detectors (below), 'what is incorrectly termed 'IR spectroscopy'; and by thermoelectric's complement, Raman (Laser Lidar) spectroscopy (above). Notice O2 and N2 (some 99% of the dry atmosphere) are only detected by means of Raman spectroscopy. This is due to them both having their one (and only) vibrational mode being non-thermoelectric: they both have only symmetric vibrational modes, with no electric dipole moments to generate, by the thermopile, an electric charge, and so a
Showing posts from April, 2016
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I have now published my updated theory of the atmosphere. Augmenting 19th Century Thermoelectric Greenhouse Theory with 20th Century Quantum Mechanics Raman Spectroscopy: Towards a Coherent Radiation Theory of the Atmosphere If the non-greenhouse gases oxygen (O2) and nitrogen (N2) – some 99% of the dry atmosphere – do not block (absorb or emit) infrared radiation - as assumed in greenhouse theory - there is a contradiction in thermodynamics, which states all substances above absolute zero radiate thermal infrared radiation. Converse to the above, if O2 and N2 do radiate infrared - in accordance with thermal dynamics - there is a contradiction in greenhouse theory as greenhouse theory assumes, as a key implied premise - derived by the Tyndall thermopile experiment - O2 and N2 are non-greenhouse gases and do not radiate or absorb any IR. This is a catastrophe: not the ‘ultraviolet’ one, but an infrared one. It is the infrared catastrophe (my words).
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I would like to share with you a paradox I have uncovered during my investigation into thermoelectrics ('IR spectroscopy') that I call the albedo-emissivity paradox. The albedo of snow is very high as it reflects light, while at the same time the emissivity of snow is also very high (near 1, which implies it absorbs and emits IR radiation, and does not reflect IR (thermal) radiation). Snow and ice are near perfect black bodies. But, does snow really not reflect IR (heat)? In any other context IR is thermo radiation, and related to heat and temperature. Snow absorbs this IR but does not reflect it? Can this be true? I don't think so. Black painted or dyed snow will melt faster that white pure snow. I don't think anyone has discussed this paradox. Where have I - or scientists gone wrong? I have a possible answer to this, and the clew is aluminium and other shiny metals - all of which all have low emissivities - next to 0. Other materials don't have su